PhD position: Conformationally Controlled Chemistry in the Gas Phase at the University of Basel (Switzerland).
About the Employer University of Basel ranks among the world’s one hundred best universities and boasts a top-ten place among German-speaking universities.
Project Description A PhD position is available in the group of Prof. Stefan Willitsch at the University of Basel (Switzerland) within our controlled chemistry research programme. The project aims at controlling and exploring the role of individual molecular conformations on the chemical reactivity and dynamics of reactions in the gas phase.
The relationship between structure and reactivity is one of the central tenets of chemistry. In spite of the long history of inquiries into this problem, there is still a glaring lack of experimental data on structure–reactivity relationships studied under single‒collision conditions. In particular, complex molecules possess multiple conformers (rotational isomers) that interconvert through hindered rotations about covalent bonds. It is well established that the molecular conformation can have a pronounced influence on the chemical reactivity. However, in room‒temperature solution–or gas‒phase experiments, conformers often interconvert into one another through thermal motion leading to mixtures in which all specificity is lost.
The present PhD project will employ new experimental methods developed by our group for studying chemical reactions of individual conformers in the gas phase. Such gas‒phase studies are the cleanest and most accurate approach to disentangle different aspects contributing to chemical reactivity and are, therefore, vital for understanding the microscopic details of chemical processes. The present studies will focus on reactions of specific conformations of prototypical organic molecules with with conformationally selected molecular ions in order to gain an in-depth understanding of fundamental aspects of conformer–specific reactivity in selected model systems.
Further Information
L. Ploenes, P. Straňak, A. Mishra, X. Liu, J. Pérez-Ríos and S. Willitsch, "Collisional alignment and molecular rotation control chemi‑ionization of individual conformers", Nat. Chem. 16 (2024), 1876
L. Xu, J. Toscano, and S. Willitsch, "Trapping and sympathetic cooling of conformationally selected molecular ions", Phys. Rev. Lett. 132, 083001(2024)
A. Kilaj, J. Wang, P. Straňak, M. Schwilk, U. Rivero, L. Xu, O. A v. Lilienfeld, J. Küpper, and S. Willitsch, "Conformer–specific polar cycloaddition of dibromobutadiene with trapped propene ions", Nat. Commun. 12 (2021), 6047
Consult the group’s website at www.coldions.chemie.unibas.ch or contact Prof. Stefan Willitsch.
Requirements
Applicants should have (or soon obtain) a masters degree in physical chemistry, atomic/molecular/chemical physics, or a related field.
Job Details
Title: PhD position: Conformationally Controlled Chemistry in the Gas Phase at the University of Basel (Switzerland)
Employer: University of Basel
Location: Petersplatz 1 Basel, Switzerland
Published: 2026-06-16
Application deadline: Unspecified
Job type: PhD
Field: Molecular Chemistry, , Organic Chemistry, , Physical Chemistry, , Experimental Physics, , Chemical Physics, and 2 more Atomic, Molecular and Optical Physics, Spectroscopy
#J-18808-Ljbffr
About the Employer University of Basel ranks among the world’s one hundred best universities and boasts a top-ten place among German-speaking universities.
Project Description A PhD position is available in the group of Prof. Stefan Willitsch at the University of Basel (Switzerland) within our controlled chemistry research programme. The project aims at controlling and exploring the role of individual molecular conformations on the chemical reactivity and dynamics of reactions in the gas phase.
The relationship between structure and reactivity is one of the central tenets of chemistry. In spite of the long history of inquiries into this problem, there is still a glaring lack of experimental data on structure–reactivity relationships studied under single‒collision conditions. In particular, complex molecules possess multiple conformers (rotational isomers) that interconvert through hindered rotations about covalent bonds. It is well established that the molecular conformation can have a pronounced influence on the chemical reactivity. However, in room‒temperature solution–or gas‒phase experiments, conformers often interconvert into one another through thermal motion leading to mixtures in which all specificity is lost.
The present PhD project will employ new experimental methods developed by our group for studying chemical reactions of individual conformers in the gas phase. Such gas‒phase studies are the cleanest and most accurate approach to disentangle different aspects contributing to chemical reactivity and are, therefore, vital for understanding the microscopic details of chemical processes. The present studies will focus on reactions of specific conformations of prototypical organic molecules with with conformationally selected molecular ions in order to gain an in-depth understanding of fundamental aspects of conformer–specific reactivity in selected model systems.
Further Information
L. Ploenes, P. Straňak, A. Mishra, X. Liu, J. Pérez-Ríos and S. Willitsch, "Collisional alignment and molecular rotation control chemi‑ionization of individual conformers", Nat. Chem. 16 (2024), 1876
L. Xu, J. Toscano, and S. Willitsch, "Trapping and sympathetic cooling of conformationally selected molecular ions", Phys. Rev. Lett. 132, 083001(2024)
A. Kilaj, J. Wang, P. Straňak, M. Schwilk, U. Rivero, L. Xu, O. A v. Lilienfeld, J. Küpper, and S. Willitsch, "Conformer–specific polar cycloaddition of dibromobutadiene with trapped propene ions", Nat. Commun. 12 (2021), 6047
Consult the group’s website at www.coldions.chemie.unibas.ch or contact Prof. Stefan Willitsch.
Requirements
Applicants should have (or soon obtain) a masters degree in physical chemistry, atomic/molecular/chemical physics, or a related field.
Job Details
Title: PhD position: Conformationally Controlled Chemistry in the Gas Phase at the University of Basel (Switzerland)
Employer: University of Basel
Location: Petersplatz 1 Basel, Switzerland
Published: 2026-06-16
Application deadline: Unspecified
Job type: PhD
Field: Molecular Chemistry, , Organic Chemistry, , Physical Chemistry, , Experimental Physics, , Chemical Physics, and 2 more Atomic, Molecular and Optical Physics, Spectroscopy
#J-18808-Ljbffr
PhD position: Conformationally Controlled Chemistry in the Gas Phase at the University of Basel[...] Arbeitgeber: Emerging Scholars Council
Die Helmut Schmidt Universität bietet eine herausragende Arbeitsumgebung für wissenschaftliche Mitarbeiterinnen und Mitarbeiter, die sich für innovative Forschung im Bereich der Elektrotechnik und Signalverarbeitung interessieren. Mit flexiblen Arbeitszeiten, umfangreichen Fortbildungsmöglichkeiten und einer starken Unterstützung für die berufliche Weiterentwicklung, einschließlich der Möglichkeit zur Promotion, ist die Universität ein attraktiver Arbeitgeber in Hamburg. Zudem profitieren Sie von einer positiven Arbeitskultur, die Gleichstellung und Vielfalt fördert, sowie von zahlreichen Vorteilen wie einem DeutschlandJobTicket und kostengünstigen Verpflegungsmöglichkeiten auf dem Campus.
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